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石墨烯:用于锂存储的二维平台。

Graphene: a two-dimensional platform for lithium storage.

机构信息

School of Chemistry and Chemical Engineering, Shanghai JiaoTong University, Dongchuan Road 800, 200240 Shanghai, PR China.

出版信息

Small. 2013 Apr 22;9(8):1173-87. doi: 10.1002/smll.201203155. Epub 2013 Mar 13.

Abstract

Lithium ion batteries (LIBs) have attracted great attention due to their high energy density, low maintenance requirements, and relatively low self-discharge. Since the electrode materials hold the key for the electrochemical performance of LIBs, the design and synthesis of unconventional electrode materials with high lithium-storage capacities are the current focus in LIB research. In the last few years, a great deal of effort has been directed toward graphene as the electrode material for LIBs owing to its high intrinsic surface area, high electrical conductivity, and good compatibility with other electrochemically active components. This review paper outlines the componential and structural design for graphene-based hybrids in LIBs with enhanced electrochemical performance. The typical fabrication methods and structure-property relationships of these hybrids are discussed.

摘要

锂离子电池(LIBs)因其高能量密度、低维护要求和相对较低的自放电而受到极大关注。由于电极材料是 LIBs 电化学性能的关键,因此设计和合成具有高储锂容量的非常规电极材料是当前 LIB 研究的重点。在过去的几年中,由于石墨烯具有高的本征比表面积、高导电性以及与其他电化学活性组件的良好兼容性,因此它作为 LIBs 的电极材料引起了极大的关注。本文概述了用于提高 LIB 电化学性能的基于石墨烯的复合材料的组成和结构设计。讨论了这些复合材料的典型制备方法和结构-性能关系。

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