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胆甾相液晶中的一阶连续弗雷德里克兹转变

First-order and continuous Fréedericksz transitions in cholesteric liquid crystals.

作者信息

Val'kov A Yu, Aksenova E V, Romanov V P

机构信息

Saint Petersburg State University, Department of Physics, Ul'yanovskaya 1, Petrodvoretz, Saint Petersburg 198504, Russia.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Feb;87(2):022508. doi: 10.1103/PhysRevE.87.022508. Epub 2013 Feb 21.

Abstract

The Fréedericksz transition in twist cells of cholesteric liquid crystals with a finite surface energy is considered. It is shown that this transition can be either of the second order or of the first order depending on the values of the Frank constants, pitch, surface energies, and the cell thickness. A simple criterion that determines the order of the phase transition is obtained. By numerically minimizing the free energy of the liquid-crystal pattern the distribution of the director in the presence of the external electric field is calculated. For this purpose the polar angle of the director was presented as a partial sum of the Fourier series and of the appropriate function. The azimuthal angle was eliminated using Euler-Lagrange equations. Calculations were performed for different sets of liquid-crystal parameters which provide the phase transition of the first and of the second order. The numerical results are in a good agreement with theoretical formulas based on the Landau-type theory.

摘要

研究了具有有限表面能的胆甾型液晶扭曲盒中的弗雷德里克斯转变。结果表明,根据弗兰克常数、螺距、表面能和盒厚度的值,这种转变可以是二阶的,也可以是一阶的。得到了一个确定相变阶次的简单判据。通过数值最小化液晶图案的自由能,计算了外电场存在时指向矢的分布。为此,将指向矢的极角表示为傅里叶级数和适当函数的部分和。利用欧拉-拉格朗日方程消除了方位角。对提供一阶和二阶相变的不同液晶参数集进行了计算。数值结果与基于朗道型理论的理论公式吻合良好。

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