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自适应流体注入多孔薄膜,具有可调透明度和润湿性。

Adaptive fluid-infused porous films with tunable transparency and wettability.

机构信息

School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA.

出版信息

Nat Mater. 2013 Jun;12(6):529-34. doi: 10.1038/nmat3598. Epub 2013 Apr 7.

Abstract

Materials that adapt dynamically to environmental changes are currently limited to two-state switching of single properties, and only a small number of strategies that may lead to materials with continuously adjustable characteristics have been reported. Here we introduce adaptive surfaces made of a liquid film supported by a nanoporous elastic substrate. As the substrate deforms, the liquid flows within the pores, causing the smooth and defect-free surface to roughen through a continuous range of topographies. We show that a graded mechanical stimulus can be directly translated into finely tuned, dynamic adjustments of optical transparency and wettability. In particular, we demonstrate simultaneous control of the film's transparency and its ability to continuously manipulate various low-surface-tension droplets from free-sliding to pinned. This strategy should make possible the rational design of tunable, multifunctional adaptive materials for a broad range of applications.

摘要

目前,能够动态适应环境变化的材料仅限于单属性的两态切换,而且仅有少数可能导致具有连续可调特性的材料的策略被报道过。在这里,我们介绍一种由纳米多孔弹性基底支撑的液膜制成的自适应表面。随着基底的变形,液体在孔内流动,使光滑无缺陷的表面通过连续的形貌变化而变得粗糙。我们表明,梯度机械刺激可以直接转化为对光学透明度和润湿性的精细动态调节。具体而言,我们演示了对薄膜的透明度及其连续控制能力的同时调节,这种能力可以将各种低表面张力的液滴从自由滑动到固定状态进行连续操纵。这种策略应该能够为广泛的应用领域设计出可调谐的多功能自适应材料。

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