MOE Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China.
Nanoscale. 2013 May 21;5(10):4056-69. doi: 10.1039/c3nr00607g.
Electrochemical synthesis represents a highly efficient method for the fabrication of nanostructured energy materials, and various nanostructures, such as nanorods, nanowires, nanotubes, nanosheets, dendritic nanostructures, and composite nanostructures, can be easily fabricated with advantages of low cost, low synthetic temperature, high purity, simplicity, and environmental friendliness. The electrochemical synthesis, characterization, and application of electrochemical energy nanomaterials have advanced greatly in the past few decades, allowing an increasing understanding of nanostructure-property-performance relationships. Herein, we highlight some recent progress in the electrochemical synthesis of electrochemical energy materials with the assistance of additives and templates in solution or grafted onto metal or conductive polymer supports, with special attention to the effects on surface morphologies, structures and, more importantly, electrochemical performance. The methodology for preparing novel electrochemical energy nanomaterials and their potential applications has been summarized. Finally, we outline our personal perspectives on the electrochemical synthesis and applications of electrochemical energy nanomaterials.
电化学合成代表了一种高效的制备纳米结构能源材料的方法,各种纳米结构,如纳米棒、纳米线、纳米管、纳米片、树枝状纳米结构和复合纳米结构,都可以通过低成本、低温合成、高纯度、简单和环保等优势来轻松制备。在过去的几十年中,电化学能源纳米材料的电化学合成、表征和应用取得了很大的进展,使人们对纳米结构-性能-性能之间的关系有了越来越深入的了解。在此,我们重点介绍了在溶液中添加添加剂和模板或接枝到金属或导电聚合物载体上辅助电化学合成电化学能源材料方面的一些最新进展,特别关注了对表面形态、结构的影响,更重要的是对电化学性能的影响。总结了制备新型电化学能源纳米材料的方法及其潜在应用。最后,我们概述了我们对电化学合成和应用电化学能源纳米材料的个人观点。