镍铁氢化酶的 Ni-Ru 模拟物催化氢气生成涉及质子耦合电子转移步骤。
Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.
机构信息
Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France.
出版信息
Chem Commun (Camb). 2013 Jun 4;49(44):5004-6. doi: 10.1039/c3cc40987b. Epub 2013 Apr 23.
PMID:23612503
Abstract
A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases Ni(xbsms)Ru(C6Me6)Cl proceeds through proton-coupled electron transfer steps.
摘要
一项结合电化学和理论研究表明，通过 NiFe 氢化酶活性位点结构模拟物 Ni(xbsms)Ru(C6Me6)Cl 催化的弱酸析氢反应是通过质子耦合电子转移步骤进行的。
Zotero 插件