CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, PR China.
Chem Commun (Camb). 2013 Jun 7;49(45):5213-5. doi: 10.1039/c3cc41545g.
Novel DNA-MMT hybrid supported metal nanoparticle catalysts, such as Pt/DNA-MMT, Pd/DNA-MMT, Au/DNA-MMT, were prepared for application in highly selective aerobic oxidation of primary alcohols to aldehydes, acids and esters, respectively. Taking advantage of the water-soluble reversibility of these catalysts, all the transformations could be performed smoothly in water and reuse of the catalysts has also been accomplished by a very simple phase separation process.
新型 DNA-MMT 杂化负载金属纳米粒子催化剂，如 Pt/DNA-MMT、Pd/DNA-MMT、Au/DNA-MMT，被制备用于在高度选择性的伯醇有氧氧化为醛、酸和酯的反应中应用。利用这些催化剂在水中的水溶性可逆性，所有的转化都可以在水中顺利进行，并且通过非常简单的相分离过程实现了催化剂的重复使用。
