顺式-氯（甲胺）-双（丙烷-1,3-二胺）-钴（III）二氯化物一水合物
cis-Chlorido(methyl-amine)-bis-(propane-1,3-diamine)-cobalt(III) dichloride monohydrate.
作者信息
Maheshwaran Velusamy, Manjunathan Munisamy, Anbalagan Krishnamoorthy, Thiruselvam Viswanathan, Ponnuswamy Mondikalipudur Nanjappagounder
机构信息
Centre of Advanced Study in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai 600 025, India.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 13;69(Pt 4):m205-6. doi: 10.1107/S1600536813006442. Print 2013 Apr 1.
In the title compound, [CoCl(CH5N)(C3H10N2)2]Cl2·H2O, the Co(III) ion has an octa-hedral coordination environment and is surrounded by four N atoms of two propane-1,3-diamine ligands in the equatorial plane, with another N atom of the methylamine ligand and a Cl atom occupying the axial positions. The crystal packing is stabilized by inter-molecular N-H⋯O, N-H⋯Cl, and O-H⋯Cl inter-actions, generating a three-dimensional network.
在标题化合物[CoCl(CH₅N)(C₃H₁₀N₂)₂]Cl₂·H₂O中，Co(III)离子具有八面体配位环境，在赤道平面上被两个1,3 - 丙二胺配体的四个N原子所包围，甲胺配体的另一个N原子和一个Cl原子占据轴向位置。晶体堆积通过分子间的N - H⋯O、N - H⋯Cl和O - H⋯Cl相互作用得以稳定，形成三维网络。
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