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对来自撒丁岛的滨藜 Atriplex halimus L. 的植物化学研究。

Phytochemical investigation on Atriplex halimus L. from Sardinia.

机构信息

a Department of Pharmaceutical and Pharmacological Sciences , University of Padova , via Marzolo 5, 35100 , Padova , Italy.

出版信息

Nat Prod Res. 2013 Oct;27(20):1940-4. doi: 10.1080/14786419.2013.793684. Epub 2013 May 2.

Abstract

In this study, we reported the phytochemical composition of the aerial parts of Atriplex halimus L. collected from Sardinia. This species is a halophytic shrub, typical of the Mediterranean Basin. Four new glycosylated flavonoids were isolated and their structures were elucidated on the basis of 1D, 2D NMR and MS spectra as 3',5'-dimethoxymyricetin-3-O-β-D-xylopyranosyl-7-O-fucopyranosyl-(1 → 3)-β-D-glucopyranoside (1), 3'-methoxyquercetin-7-O-β-D-fucopyranosyl-(1 → 3)-β-d-glucopyranosyl-3-O-β-xylopyranosyl-(1 → 4)-β-xylopyranoside (2), 3'-methoxyquercetin-7-O-α-l-rhamnopyranosyl-3-O-α-arabinofuranosyl-(1 → 6)-β-D-glucopyranoside (3) and 3',5'-dimethoxymyricetin-7-O-fucopyranosyl-(1 → 3)-β-D-glucopyranoside (4). LC-MS(n) analysis on the extract revealed the presence of other myricetin, quercetin, isorhamnetin glycosides, simple phenolic acids and esters.

摘要

在这项研究中,我们报道了来自撒丁岛的滨藜(Atriplex halimus L.)地上部分的植物化学成分。该物种是一种典型的地中海盆地的盐生灌木。从滨藜中分离得到了四个新的糖基化黄酮类化合物,并根据 1D、2D NMR 和 MS 光谱确定了它们的结构,分别为 3',5'-二甲氧基杨梅素-3-O-β-D-木吡喃糖苷-7-O-岩藻糖基-(1 → 3)-β-D-吡喃葡萄糖苷(1)、3'-甲氧基槲皮素-7-O-β-D-岩藻糖基-(1 → 3)-β-D-吡喃葡萄糖基-3-O-β-吡喃木糖苷-(1 → 4)-β-吡喃木糖苷(2)、3'-甲氧基槲皮素-7-O-α-L-鼠李吡喃糖苷基-3-O-α-阿拉伯呋喃糖基-(1 → 6)-β-D-吡喃葡萄糖苷(3)和 3',5'-二甲氧基杨梅素-7-O-岩藻糖基-(1 → 3)-β-D-吡喃葡萄糖苷(4)。提取物的 LC-MS(n) 分析显示还存在其他杨梅素、槲皮素、异鼠李素糖苷、简单酚酸和酯类化合物。

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