Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064 PR China.
J Org Chem. 2013 Jun 7;78(11):5723-30. doi: 10.1021/jo400527r. Epub 2013 May 10.
Diaryliodonium salts are employed to directly quaternize N-substituted imidazoles by using a copper catalyst to construct aryl imidazolium salts in moderate to excellent yields. This transformation is tolerant to a broad range of functional groups and provides a straightforward, efficient, and versatile route to synthesize aryl imidazolium as well as triazolium salts, especially the unsymmetric version.
二芳基碘𬭩盐被用于通过使用铜催化剂直接季铵化 N-取代的咪唑，以中等至优异的产率构建芳基咪唑鎓盐。这种转化对广泛的官能团具有耐受性，并提供了一种直接、高效和通用的方法来合成芳基咪唑鎓盐和三唑鎓盐，特别是不对称版本。
