Laboratory for Multifunctional Materials, Department of Materials, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland.
Dalton Trans. 2013 Sep 21;42(35):12554-68. doi: 10.1039/c3dt50610j.
Among all the functional materials, ZnO plays an outstanding role in terms of chemical and physical properties, but also in terms of morphological variety and the number of reported synthesis approaches. Complex shapes and hierarchical architectures make ZnO a perfect example to study chemical and crystallization mechanisms. In this review article, we will discuss the nucleation and growth of ZnO nanostructures in liquid media by classical and non-classical (i.e., particle-based) crystallization pathways. We elaborate the chemical conditions and parameters that are responsible for the occurrence of one or the other pathway.
在所有的功能材料中，氧化锌无论在化学和物理性质方面，还是在形态多样性和报道的合成方法数量方面，都表现得尤为突出。复杂的形状和层次结构使氧化锌成为研究化学和结晶机制的理想范例。在这篇综述文章中，我们将讨论通过经典和非经典（即基于颗粒的）结晶途径在液体介质中氧化锌纳米结构的成核和生长。我们详细阐述了导致一种或另一种途径发生的化学条件和参数。
