通过直接三氟甲硫基化形成C-SCF₃键。 - Suppr

Suppr

超能文献

Formation of C-SCF3 bonds through direct trifluoromethylthiolation.

作者信息

Tlili Anis, Billard Thierry

机构信息

Leibniz-Institut für Katalyse, Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany.

出版信息

Angew Chem Int Ed Engl. 2013 Jul 1;52(27):6818-9. doi: 10.1002/anie.201301438. Epub 2013 May 9.

DOI:10.1002/anie.201301438

PMID:23657900

Abstract

摘要

相似文献

Formation of C-SCF3 bonds through direct trifluoromethylthiolation.通过直接三氟甲硫基化形成C-SCF₃键。

Angew Chem Int Ed Engl. 2013 Jul 1;52(27):6818-9. doi: 10.1002/anie.201301438. Epub 2013 May 9.

Copper-catalyzed trifluoromethylthiolation of primary and secondary alkylboronic acids.铜催化的伯烷基硼酸和仲烷基硼酸的三氟甲硫基化反应。

Org Lett. 2014 Sep 19;16(18):4738-41. doi: 10.1021/ol502132j. Epub 2014 Sep 8.

Copper-catalyzed trifluoromethylthiolation of aryl halides with diverse directing groups.铜催化的带有不同导向基团的芳基卤代物的三氟甲基硫代反应。

Org Lett. 2014 Aug 1;16(15):3942-5. doi: 10.1021/ol501742a. Epub 2014 Jul 18.

Trifluoromethanesulfonyl hypervalent iodonium ylide for copper-catalyzed trifluoromethylthiolation of enamines, indoles, and β-keto esters.三氟甲磺酸酯高碘𬭩叶立德用于铜催化的烯胺、吲哚和β-酮酯的三氟甲硫基化反应。

J Am Chem Soc. 2013 Jun 19;135(24):8782-5. doi: 10.1021/ja402455f. Epub 2013 Jun 11.

Mild electrophilic trifluoromethylthiolation of ketones with trifluoromethanesulfanamide.酮与三氟甲硫酰胺的温和亲电三氟甲硫基化反应。

Org Biomol Chem. 2015 Jul 7;13(25):6992-9. doi: 10.1039/c5ob00960j. Epub 2015 Jun 1.

Difluorocarbene-Derived Trifluoromethylthiolation and [(18)F]Trifluoromethylthiolation of Aliphatic Electrophiles.二氟卡宾衍生的脂肪族亲电试剂的三氟甲硫基化反应及[(18)F]三氟甲硫基化反应

Angew Chem Int Ed Engl. 2015 Nov 2;54(45):13236-40. doi: 10.1002/anie.201505446. Epub 2015 Sep 21.

Oxidative trifluoromethylation and trifluoromethylthiolation reactions using (trifluoromethyl)trimethylsilane as a nucleophilic CF3 source.使用（三氟甲基）三甲基硅烷作为亲核 CF3 源的氧化三氟甲基化和三氟甲硫基化反应。

Acc Chem Res. 2014 May 20;47(5):1513-22. doi: 10.1021/ar4003202. Epub 2014 Apr 28.

Shelf-stable electrophilic reagents for trifluoromethylthiolation.稳定货架的亲电子三氟甲硫基化试剂。

Acc Chem Res. 2015 May 19;48(5):1227-36. doi: 10.1021/acs.accounts.5b00047. Epub 2015 May 7.

Ruthenium-catalyzed regioselective allylic trifluoromethylthiolation reaction.钌催化的区域选择性烯丙基三氟甲硫基化反应。

J Org Chem. 2014 Dec 19;79(24):12106-10. doi: 10.1021/jo5019393. Epub 2014 Sep 18.

An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes.一种高效实用的α-卤代酮/α-卤代芳基甲烷三氟甲硫基化方法。

Org Biomol Chem. 2015 Jul 7;13(25):6935-9. doi: 10.1039/c5ob00858a. Epub 2015 Jun 4.

引用本文的文献

Recent trends in dehydroxylative trifluoro-methylation, -methoxylation, -methylthiolation, and -methylselenylation of alcohols.醇的脱羟基三氟甲基化、甲氧基化、甲硫基化和甲硒基化的最新趋势

RSC Adv. 2021 Dec 13;11(62):39593-39606. doi: 10.1039/d1ra05018d. eCollection 2021 Dec 6.

Gold (I/III)-Catalyzed Trifluoromethylthiolation and Trifluoromethylselenolation of Organohalides.金（I/III）催化的卤代烃的三氟甲基硫代和三氟甲基硒代反应。

Angew Chem Int Ed Engl. 2022 Mar 14;61(12):e202115687. doi: 10.1002/anie.202115687. Epub 2022 Feb 3.

Trifluoromethylthiolation, Trifluoromethylation, and Arylation Reactions of Difluoro Enol Silyl Ethers.二氟烯醇硅醚的三氟甲硫基化、三氟甲基化及芳基化反应

J Org Chem. 2020 Jul 2;85(13):8311-8319. doi: 10.1021/acs.joc.0c01030. Epub 2020 May 26.

Late-stage trifluoromethylthiolation of benzylic C-H bonds.苄位 C-H 键的晚期三氟甲基化反应。

Nat Commun. 2019 Oct 25;10(1):4867. doi: 10.1038/s41467-019-12844-9.

-Trifluoromethylthiolated Sulfonimidamides and Sulfoximines: Anti-microbial, Anti-mycobacterial, and Cytotoxic Activity.-三氟甲硫基化磺酰亚胺酰胺和亚砜亚胺：抗菌、抗分枝杆菌及细胞毒性活性

ACS Med Chem Lett. 2019 Sep 11;10(10):1457-1461. doi: 10.1021/acsmedchemlett.9b00285. eCollection 2019 Oct 10.

Recent advances in transition-metal-catalyzed incorporation of fluorine-containing groups.过渡金属催化含氟基团引入的最新进展。

Beilstein J Org Chem. 2019 Sep 23;15:2213-2270. doi: 10.3762/bjoc.15.218. eCollection 2019.

Trifluoromethylthiolation-arylation of diazocarbonyl compounds by modified Hooz multicomponent coupling.通过改进的胡兹多组分偶联实现重氮羰基化合物的三氟甲硫基化-芳基化反应

Chem Sci. 2019 May 6;10(23):5990-5995. doi: 10.1039/c9sc00829b. eCollection 2019 Jun 21.

Synthesis of Aryl Triflones through the Trifluoromethanesulfonylation of Benzynes.通过苯炔的三氟甲磺酰化反应合成芳基三氟甲磺酸盐

ChemistryOpen. 2018 Feb 27;7(2):204-211. doi: 10.1002/open.201700204. eCollection 2018 Feb.

2-Diazo-1-phenyl-2-((trifluoromethyl)sulfonyl)ethan-1-one: Another Utility for Electrophilic Trifluoromethylthiolation Reactions.2-重氮基-1-苯基-2-((三氟甲基)磺酰基)乙-1-酮：亲电三氟甲硫基化反应的另一种应用。

ChemistryOpen. 2016 Jan 28;5(3):188-191. doi: 10.1002/open.201500225. eCollection 2016 Jun.

Difluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysis.用于铜催化下亲电二氟甲基硫醇化反应的二氟甲磺酰基高价碘叶立德

R Soc Open Sci. 2016 May 25;3(5):160102. doi: 10.1098/rsos.160102. eCollection 2016 May.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验