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[Au(NHC)X](NHC = N-杂环卡宾,X = Cl、Br、I)配合物的简便合成。

Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes.

机构信息

EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, UK.

出版信息

Chem Commun (Camb). 2013 Jun 21;49(49):5541-3. doi: 10.1039/c3cc43076f.

DOI:10.1039/c3cc43076f
PMID:23677147
Abstract

An improved protocol for the synthesis of [Au(NHC)X] (X = Cl, Br, I) complexes is reported. This versatile one-step synthetic methodology proceeds under mild conditions, in air, using technical grade solvents, is scalable and is applicable to a wide range of imidazolium and imidazolidinium salts.

摘要

报道了一种改进的[Au(NHC)X](X = Cl、Br、I)配合物合成的方案。这种多功能的一步合成方法在温和条件下、空气中、使用工业级溶剂进行,可规模化,并适用于广泛的咪唑鎓和咪唑烷鎓盐。

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