电化学方法制备薄膜状共轭微孔聚合物及其在有机电子学中的应用。
Electrochemical route to fabricate film-like conjugated microporous polymers and application for organic electronics.
机构信息
State Key Laboratory of Supramolecular, Structure and Materials, Jilin University, Qianjin Avenue, Changchun 130012, P. R. China.
出版信息
Adv Mater. 2013 Jul 5;25(25):3443-8. doi: 10.1002/adma.201300839. Epub 2013 May 21.
Film-like conjugated microporous polymers (CMPs) are fabricated by the novel strategy of carbazole-based electropolymerization. The CMP film storing a mass of counterions acting as an anode interlayer provides a significant power-conversion efficiency of 7.56% in polymer solar cells and 20.7 cd A(-1) in polymer light-emitting diodes, demonstrating its universality and potential as an electrode interlayer in organic electronics.
通过咔唑基电化学聚合的新策略，制备出了类似电影的共轭微孔聚合物（CMPs）。CMP 薄膜储存了大量的抗衡离子，作为阳极层间材料，在聚合物太阳能电池中提供了 7.56%的显著功率转换效率，在聚合物发光二极管中提供了 20.7 cd A(-1)的亮度，证明了其在有机电子学中作为电极层间材料的通用性和潜力。
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