Department of Biotechnology, SGB Amravati University, Amravati 444 602, Maharashtra, India.
IET Nanobiotechnol. 2013 Mar;7(1):28-32. doi: 10.1049/iet-nbt.2012.0002.
Till date several methods of chemical synthesis of silver nanoparticles (AgNps) are known. Most of the protocol dealing with the chemical synthesis of AgNps involves high pressure, temperature, energy and technical skills. Thus, a method with much greener approach is the need of the hour. Accordingly, the authors have developed a method that is cost-effective, energy-efficient and easy method for the synthesis of AgNps. The AgNps were synthesised by using white sugar and sodium hydroxide (NaOH) in the presence of sunlight. These nanoparticles were characterised by visual observation, ultraviolet-visible (UV-vis) spectrophotometry, Fourier transform infrared (FTIR), nanoparticle tracking and analysis (NTA) and transmission electron microscopy (TEM). The effect of NaOH on the rate of AgNps synthesis was also studied. Formation of AgNps was primarily detected by change in colour of reaction mixture from colourless to yellow after treatment with 1 mM silver salt (AgNO3). UV-vis spectroscopy showed peak at 409 nm. NTA revealed the polydispersed nature of nanoparticles, 15-30 nm in diameter. FTIR showed the presence of gluconic acid as capping agent, which increases the stability of AgNps in the colloids. TEM demonstrated the presence of spherical AgfNps in the range of 10-25 nm. The present method confirms the synthesis of AgNps by using white sugar and NaOH. This method is simple, eco-friendly and economically sustainable, making it amenable to large-scale industrial production of AgNps.
迄今为止,已经有几种化学合成银纳米粒子(AgNps)的方法。大多数涉及 AgNps 化学合成的方案都需要高压、高温、高能量和高技术技能。因此,需要一种更加环保的方法。根据这一情况,作者开发了一种具有成本效益、节能且易于合成 AgNps 的方法。AgNps 是通过在阳光存在下使用白糖和氢氧化钠(NaOH)合成的。这些纳米粒子通过肉眼观察、紫外-可见(UV-vis)分光光度法、傅里叶变换红外(FTIR)、纳米颗粒跟踪和分析(NTA)以及透射电子显微镜(TEM)进行了表征。还研究了 NaOH 对 AgNps 合成速率的影响。AgNps 的形成主要通过 1mM 银盐(AgNO3)处理后反应混合物从无色变为黄色来检测。紫外-可见光谱显示在 409nm 处有一个峰。NTA 显示出纳米颗粒的多分散性质,直径为 15-30nm。FTIR 显示葡萄糖酸作为封端剂的存在,这增加了 AgNps 在胶体中的稳定性。TEM 证明了存在 10-25nm 范围内的球形 AgfNps。本方法证实了使用白糖和 NaOH 合成 AgNps。该方法简单、环保且经济可持续,使其适用于 AgNps 的大规模工业生产。