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通过可逆的分子间质子转移实现了酸敏两性分子和机械变色。

Stress acidulated amphoteric molecules and mechanochromism via reversible intermolecular proton transfer.

机构信息

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun, Jilin 130012, PR China.

出版信息

Chem Commun (Camb). 2013 Jul 28;49(59):6587-9. doi: 10.1039/c3cc42747a.

Abstract

Stress has been proved to acidulate amphoteric molecules and promote an intermolecular proton transfer, which results in a significant absorption and emission change. The stress acidulated amphoteric molecules open a new avenue for developing mechanochromic materials and anticipate many broad applications such as stress/pressure sensors and rewritable media.

摘要

已有研究证实,压力可以酸化两性分子并促进分子间质子转移,从而导致显著的吸收和发射变化。压力酸化两性分子为开发机械变色材料开辟了新途径,并有望在压力/压力传感器和可重写介质等众多领域得到广泛应用。

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