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本文引用的文献

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2
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
3
Direct synthesis of 1,3-diketones by Rh-catalyzed reductive alpha-acylation of enones.通过铑催化烯酮的还原α-酰化直接合成1,3-二酮
Org Lett. 2008 Jun 19;10(12):2405-8. doi: 10.1021/ol800660y. Epub 2008 May 14.
4
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
5
Synthesis and antibacterial properties of beta-diketone acrylate bioisosteres of pseudomonic acid A.
Bioorg Med Chem Lett. 1999 Jul 5;9(13):1847-52. doi: 10.1016/s0960-894x(99)00296-6.

3-(4-Chloro-phen-yl)-1-cyclo-propyl-2-(2-fluoro-phen-yl)-5-phenyl-pentane-1,5-dione.

作者信息

Srinivasan Thothadri, Senthilkumar Govindaraj, Manikandan Haridoss, Gopalakrishnan Mannathusamy, Velmurugan Devadasan

机构信息

Centre of Advanced Study in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai 600 025, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 30;69(Pt 5):o816. doi: 10.1107/S1600536813011276. Print 2013 May 1.

DOI:10.1107/S1600536813011276
PMID:23723952
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3648332/
Abstract

In the title compound, C26H22ClFO2, the cyclo-propane ring is disordered over two orientations, with site-occupancy factors of 0.64 (2) and 0.36 (2). The major occupancy component of the cyclo-propane ring makes dihedral angles of 47.6 (7), 50.4 (7) and 65.4 (7)° with the fluoro-, chloro- and unsubstituted benzene rings, respectively [the corresponding values for the minor occupancy component are 47.6 (12), 51.0 (12) and 60.9 (12)°]. An intra-molecular C-H⋯O hydrogen bond occurs. The F and Cl atoms deviate by 0.0508 (12) and 0.0592 (7) Å from the planes of their attached benzene rings. In the crystal, C-H⋯F hydrogen bonds link the mol-ecules into chains along the b-axis direction.

摘要