三有机铝试剂促进的芳香醛到芳基酮的串联亲核加成-Oppenauer 氧化反应。
Tandem nucleophilic addition-Oppenauer oxidation of aromatic aldehydes to aryl ketones with triorganoaluminium reagents.
机构信息
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, PR China.
出版信息
Org Biomol Chem. 2013 Jul 21;11(27):4429-32. doi: 10.1039/c3ob40642c.
PMID:23736650
Abstract
In the presence of pinacolone, the in situ prepared triorganoaluminium reagents reacted with aromatic aldehydes to give ketones in moderate to high yield. We propose that the products are formed via a tandem organoaluminium reagents addition-Oppenauer oxidation sequence.
摘要
在片呐醇存在的情况下，原位制备的三有机铝试剂与芳香醛反应，以中等至高产率得到酮。我们提出产物是通过串联的有机铝试剂加成-Oppenauer 氧化序列形成的。
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