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本文引用的文献

1
Efficient synthesis of 3-arylphthalides using palladium-catalyzed arylation of aldehydes with organoboronic acids.使用钯催化的醛与硼酸酯的芳基化反应高效合成 3-芳基苯并呋喃。
J Org Chem. 2009 Dec 4;74(23):9210-3. doi: 10.1021/jo901964k.
2
A nickel catalyst for the addition of organoboronate esters to ketones and aldehydes.一种用于将有机硼酸酯加成到酮和醛上的镍催化剂。
Org Lett. 2009 Oct 1;11(19):4410-3. doi: 10.1021/ol9017613.
3
Me-bipam for enantioselective ruthenium(II)-catalyzed arylation of aldehydes with arylboronic acids.用于钌（II）催化醛与芳基硼酸对映选择性芳基化反应的Me-联苯
Angew Chem Int Ed Engl. 2009;48(24):4414-6. doi: 10.1002/anie.200901395.
4
FeCl3-catalyzed 1,2-addition reactions of aryl aldehydes with arylboronic acids.三氯化铁催化芳基醛与芳基硼酸的1,2-加成反应。
Org Lett. 2009 Jan 15;11(2):453-6. doi: 10.1021/ol802529p.
5
Copper(II) acetate-catalyzed addition of arylboronic acids to aromatic aldehydes.醋酸铜（II）催化芳基硼酸与芳香醛的加成反应。
J Org Chem. 2009 Jan 16;74(2):943-5. doi: 10.1021/jo802225j.
6
Sterically hindered benzophenones via rhodium-catalyzed oxidative arylation of aldehydes.通过铑催化醛的氧化芳基化反应合成空间位阻二苯甲酮
J Org Chem. 2008 Oct 3;73(19):7800-2. doi: 10.1021/jo801460w. Epub 2008 Aug 28.
7
Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands.使用硫醚-咪唑啉鎓卡宾配体，钯催化芳基和烯基三氟硼酸钾与醛的1,2-加成反应。
J Org Chem. 2008 Sep 5;73(17):6939-42. doi: 10.1021/jo801352h. Epub 2008 Aug 6.
8
Phosphinite- and phosphite-based Type I palladacycles as highly active catalysts for addition reactions of arylboronic acids with aldehydes, α,β-unsaturated ketones, α-ketoesters, and aldimines.基于次膦酸酯和亚磷酸酯的I型钯环配合物作为芳基硼酸与醛、α,β-不饱和酮、α-酮酯和醛亚胺加成反应的高活性催化剂。
Tetrahedron Lett. 2007 Jul 23;48(30):5283-5288. doi: 10.1016/j.tetlet.2007.05.119.
9
Orthoplatinated triarylphosphite as a highly efficient catalyst for addition reactions of arylboronic acids with aldehydes: low catalyst loading catalysis and a new tandem reaction sequence.顺式铂络合亚磷酸三芳酯作为芳基硼酸与醛加成反应的高效催化剂：低催化剂负载量催化及一种新的串联反应序列
Org Lett. 2008 Jun 19;10(12):2509-12. doi: 10.1021/ol800774c. Epub 2008 May 9.
10
Axial coordination of NHC ligands on dirhodium(II) complexes: generation of a new family of catalysts.N-杂环卡宾配体在二铑（II）配合物上的轴向配位：新型催化剂家族的生成
J Org Chem. 2008 Jun 6;73(11):4076-86. doi: 10.1021/jo800087n. Epub 2008 May 6.

芳基酮的串联合成通过芳基硼酸与醛的邻位铂化三芳基亚膦酸盐催化加成反应，然后进行氧化反应。

Aryl ketone synthesis via tandem orthoplatinated triarylphosphite-catalyzed addition reactions of arylboronic acids with aldehydes followed by oxidation.

机构信息

Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, Staten Island, New York 10314, USA.

出版信息

J Org Chem. 2010 Oct 15;75(20):6986-9. doi: 10.1021/jo101469s.

DOI:10.1021/jo101469s
PMID:20849092
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2975394/
Abstract

Tandem orthoplatinated triaryl phosphite-catalyzed addition reactions of arylboronic acids with aldehydes followed by oxidation to yield aryl ketones is described. 3-Pentanone was identified as a suitable oxidant for the tandem aryl ketone formation reaction. By using microwave energy, aryl ketones were obtained in high yields with the catalyst loading as low as 0.01%.

摘要

描述了偕二正膦酸三芳基酯催化的芳基硼酸与醛的加成反应，然后氧化得到芳基酮。已鉴定出 3-戊酮是适合用于串联芳基酮形成反应的氧化剂。通过使用微波能量，即使催化剂负载量低至 0.01%，也可以高产率获得芳基酮。