BioCircuits Institute, University of California, San Diego, La Jolla, CA 92093, USA.
Anal Chim Acta. 2013 Jun 27;785:1-15. doi: 10.1016/j.aca.2013.04.024. Epub 2013 Apr 18.
Designing reliable, fast responding, highly sensitive, and low-power consuming chemo-sensory systems has long been a major goal in chemo-sensing. This goal, however, presents a difficult challenge because having a set of chemo-sensory detectors exhibiting all these aforementioned ideal conditions are still largely un-realizable to-date. This paper presents a unique perspective on capturing more in-depth insights into the physicochemical interactions of two distinct, selectively chemically modified porous silicon (pSi) film-based optical gas sensors by implementing an innovative, based on signal processing methodology, namely the two-dimensional discrete wavelet transform. Specifically, the method consists of using the two-dimensional discrete wavelet transform as a feature extraction method to capture the non-stationary behavior from the bi-dimensional pSi rugate sensor response. Utilizing a comprehensive set of measurements collected from each of the aforementioned optically based chemical sensors, we evaluate the significance of our approach on a complex, six-dimensional chemical analyte discrimination/quantification task problem. Due to the bi-dimensional aspects naturally governing the optical sensor response to chemical analytes, our findings provide evidence that the proposed feature extractor strategy may be a valuable tool to deepen our understanding of the performance of optically based chemical sensors as well as an important step toward attaining their implementation in more realistic chemo-sensing applications.
设计可靠、快速响应、高灵敏度和低功耗的化学感应系统一直是化学感应领域的主要目标。然而,这一目标提出了一个艰巨的挑战,因为迄今为止,还没有一套化学感应探测器能够同时具备上述所有理想条件。本文提出了一种独特的视角,通过实施一种创新的基于信号处理的方法,即二维离散小波变换,深入了解两种不同的、选择性化学修饰的多孔硅(pSi)膜基光学气体传感器的物理化学相互作用。具体来说,该方法包括使用二维离散小波变换作为特征提取方法,从二维 pSi 闪耀传感器响应中捕获非平稳行为。利用从上述每一种基于光学的化学传感器收集的一套全面的测量结果,我们评估了我们的方法在一个复杂的、六维化学分析物识别/定量任务问题上的重要性。由于二维方面自然控制着光学传感器对化学分析物的响应,我们的发现提供了证据,表明所提出的特征提取策略可能是加深我们对基于光学的化学传感器性能的理解的有价值的工具,也是实现它们在更实际的化学感应应用中的重要步骤。