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从藏药唐古特乌头中分离出的三种新的酚苷。

Three new phenolic glycosides from the Tibetan medicinal plant Aconitum tanguticum.

作者信息

Xu Lu, Luo Ming, Lin Li-Me, Zhang Xiao, Li Chun, Wang Zhi-Min, Luo Yong-Ming

机构信息

Institute of Chinese Materia Medica, China Academy of Chinese Medicine Sciences, Beijing 100700, China.

出版信息

J Asian Nat Prod Res. 2013 Jul;15(7):743-9. doi: 10.1080/10286020.2013.799145. Epub 2013 Jun 14.

Abstract

Three new phenolic glycosides, such as (Z)-sinapic acid-4-O-β-d-allopyranoside (1), 3,4-dihydroxyphenethoxy-8-O-β-d-[6-O-(4-O-β-d-glucopyranosyl)-feruloyl]-glucopyranoside (2), and 4-dihydroxyphenethoxy-8-O-β-d-[6-O-(4-O-β-d-glucopyranosyl)-feruloyl]-glucopyranoside (3) were isolated from the EtOH extract of whole plant of Aconitum tanguticum (Maxim.) Stapf. The structures of the new compounds were elucidated by spectroscopic methods, and the total (1)H NMR and (13)C NMR chemical shifts were assigned.

摘要

从唐古特乌头(Maxim.)Stapf全株乙醇提取物中分离得到三种新的酚苷,即(Z)-芥子酸-4-O-β-D-阿洛吡喃糖苷(1)、3,4-二羟基苯乙氧基-8-O-β-D-[6-O-(4-O-β-D-吡喃葡萄糖基)-阿魏酰基]-吡喃葡萄糖苷(2)和4-二羟基苯乙氧基-8-O-β-D-[6-O-(4-O-β-D-吡喃葡萄糖基)-阿魏酰基]-吡喃葡萄糖苷(3)。通过光谱方法阐明了新化合物的结构,并归属了其1H NMR和13C NMR的全部化学位移。

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