在生物条件下进行铜介导的可控自由基聚合：血清中的 SET-LRP。
Copper-mediated controlled radical polymerization under biological conditions: SET-LRP in blood serum.
机构信息
Department of Chemistry, University of Warwick, CV4 7AL, Coventry, UK.
出版信息
Chem Commun (Camb). 2013 Jul 28;49(59):6608-10. doi: 10.1039/c3cc43731k.
PMID:23770731
Abstract
The polymerization of hydrophilic monomers is reported utilizing Cu(0)-mediated living radical polymerization, SET-LRP. Highly active Cu(0) is formed in situ as a result of rapid disproportionation of [Cu(I)(Me6-Tren)Br] in serum. Disproportionation and homogenous controlled radical polymerization (PDI 1.09-1.25) are performed for the first time in blood (sheep) serum.
摘要
据报道，亲水单体的聚合是利用 Cu(0)-介导的活性自由基聚合（SET-LRP）进行的。由于 [Cu(I)(Me6-Tren)Br] 在血清中快速歧化，原位形成高活性的 Cu(0)。首次在血液（绵羊）血清中进行了歧化和均相可控自由基聚合（PDI 1.09-1.25）。
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