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正向和压力延迟渗透:能源和水供应方面全球挑战的潜在解决方案。

Forward and pressure retarded osmosis: potential solutions for global challenges in energy and water supply.

机构信息

Centre for Surface Chemistry and Catalysis, Faculty of Bioengineering Sciences, Katholieke Universiteit Leuven, Kasteelpark Arenberg 23, Post Box 2461, 3001 Leuven, Belgium.

出版信息

Chem Soc Rev. 2013 Aug 21;42(16):6959-89. doi: 10.1039/c3cs60051c.

Abstract

Osmotically driven membrane processes (ODMP) have gained renewed interest in recent years and they might become a potential solution for the world's most challenging problems of water and energy scarcity. Though the concept of utilizing osmotic pressure difference between high and low salinity streams across semipermeable membranes has been explored for several decades, lack of optimal membranes and draw solutions hindered competition between forward osmosis (FO) and pressure retarded osmosis (PRO) with existing water purification and power generation technologies, respectively. Driven by growing global water scarcity and by energy cost and negative environmental impacts, novel membranes and draw solutions are being developed for ODMPs, mass and heat transfer in osmotic process are becoming better understood, and new applications of ODMPs are emerging. Therefore, OMDPs might become promising green technologies to provide clean water and clean energy from abundantly available renewable resources. This review focuses primarily on new insights into osmotic membrane transport mechanisms and on novel membranes and draw solutions that are currently being developed. Furthermore, the effects of operating conditions on the overall performance of osmotic membranes will be highlighted and future perspectives will be presented.

摘要

近年来,渗透压驱动膜过程(ODMP)重新引起了人们的兴趣,它们可能成为解决世界上水资源和能源短缺这两大难题的潜在方案。虽然利用高盐度和低盐度溶液之间的渗透压差透过半透膜的概念已经被探索了几十年,但缺乏最佳的膜和汲取液,阻碍了正向渗透(FO)和压力延迟渗透(PRO)分别与现有水净化和发电技术之间的竞争。受日益严重的全球水资源短缺以及能源成本和负面环境影响的推动,正在为 ODMP 开发新型膜和汲取液,对渗透过程中的质量和热量传递有了更深入的了解,并且出现了 ODMP 的新应用。因此,ODMP 可能成为有前途的绿色技术,可从丰富的可再生资源中提供清洁水和清洁能源。本文主要关注于对渗透膜传输机制的新见解,以及目前正在开发的新型膜和汲取液。此外,还将重点介绍操作条件对渗透膜整体性能的影响,并提出未来展望。

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