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1,2-双{2-[(4-甲氧基-亚苄基)氨基]苯基}二硫烷

1,2-Bis{2-[(4-meth-oxy-benzyl-idene)amino]-phen-yl}disulfane.

作者信息

Xin Wei

机构信息

Kingfa Scientific & Technological Coporation Limited, Guang Zhou, China 510663, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 May 15;69(Pt 6):o896. doi: 10.1107/S1600536813011598. Print 2013 Jun 1.

Abstract

The asymmetric unit of the title compound, C28H24N2O2S2, contains one-half mol-ecule, which is completed by twofold rotation symmetry with the twofold axis passing through the mid-point of the central S-S bond. The planes of the two benzene rings linked by the di-sulfide chain form a dihedral angle of 76.1 (1)°, while the planes of the two benzene rings in the benzyl-ideneaniline fragment form a dihedral angle of 48.9 (1)°. The crystal packing exhibits no significantly short inter-molecular contacts.

摘要

标题化合物C28H24N2O2S2的不对称单元包含半个分子,通过二重旋转对称性完成,二重轴穿过中心S-S键的中点。由二硫链连接的两个苯环平面形成76.1 (1)°的二面角,而苄基苯胺片段中两个苯环的平面形成48.9 (1)°的二面角。晶体堆积没有明显的短分子间接触。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eb6a/3685053/112c88edd334/e-69-0o896-fig1.jpg

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