(E)-1,5-Di-phenyl-pent-2-en-4-yn-1-one.
作者信息
Bunev Alexander S, Statsyuk Vladimir E, Utekhina Nina V, Khrustalev Victor N
机构信息
Department of Chemistry and Chemical Technology, Togliatti State University, 14 Belorusskaya St, Togliatti 445667, Russian Federation.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 May 18;69(Pt 6):o911. doi: 10.1107/S1600536813013044. Print 2013 Jun 1.
Abstract
The title compound, C17H12O, has an E conformation about the C=C bond. The C-C C-C torsion angle is 7.7 (2)°, and the mean planes of the phenyl-ethyl-enone [r.m.s. deviation = 0.059 (1) Å] and phenyl-acetyl-ene [r.m.s. deviation = 0.023 (1) Å] fragments form a dihedral angle of 14.16 (7)°. In the crystal, weak C-H⋯O inter-actions link the mol-ecules into zigzag chains propagated in [010].
摘要
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3
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J Am Chem Soc. 2002 May 15;124(19):5260-1. doi: 10.1021/ja025776+.
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J Am Chem Soc. 2002 Jan 30;124(4):526-7. doi: 10.1021/ja017037j.
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