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Chem Commun (Camb). 2013 Aug 21;49(65):7198-200. doi: 10.1039/c3cc43012j. Epub 2013 Jun 25.
The R-(+)-enantiomeric form of Dianin's compound and the S-(+)-enantiomeric form of its direct thiachroman analogue both obtained chromatographically employing a cellulose tris(3,5-dimethylphenylcarbamate) column, are shown to undergo supramolecular assembly to form a polar clathrate lattice which is stable even in the absence of a consolidating guest component.
使用纤维素三(3,5-二甲基苯基氨基甲酸酯)柱通过色谱法获得的 Dianin 化合物的 R-(+)-对映异构体和其直接噻烷类似物的 S-(+)-对映异构体都显示出超分子组装形成稳定的极性主体晶格,即使在没有稳定化客体成分的情况下也是如此。