Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Org Lett. 2013 Jul 5;15(13):3452-5. doi: 10.1021/ol4015317. Epub 2013 Jun 25.
The indium triiodide catalyzed single-stage cascade reaction of N-sulfonyl amides with hydrosilanes and two types of organosilicon nucleophiles such as silyl cyanide and silyl enolates selectively promoted deoxygenative functionalization to give α-cyanoamines and β-aminocarbonyl compounds, respectively.
三碘化铟催化的 N-磺酰基酰胺与硅烷和两种类型的有机硅亲核试剂（如氰基硅烷和硅烯醇酯）的单级级联反应，分别选择性地促进脱氧化官能化，生成α-氰基胺和β-氨基羰基化合物。
