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在向列相液晶中热力学稳定的量子点分散体。

Thermodynamically stable dispersions of quantum dots in a nematic liquid crystal.

机构信息

State Scientific Institution Institute for Single Crystals, NAS of Ukraine, 60, Lenin Ave., Kharkov, 61001, Ukraine.

出版信息

Langmuir. 2013 Jul 30;29(30):9301-9. doi: 10.1021/la401475b. Epub 2013 Jul 16.

Abstract

Using transmittance electron microscopy, fluorescence and polarizing optical microscopy, optical spectroscopy, and fluorescent correlation spectroscopy, it was shown that CdSe/ZnS quantum dots coated with a specifically designed surfactant were readily dispersed in nematic liquid crystal (LC) to form stable colloids. The mixture of an alkyl phosphonate and a dendritic surfactant, where the constituent molecules contain promesogenic units, enabled the formation of thermodynamically stable colloids that were stable for at least 1 year. Stable colloids are formed due to minimization of the distortion of the LC ordering around the quantum dots.

摘要

利用透射电子显微镜、荧光和偏光显微镜、光谱学和荧光相关光谱学,研究表明,用专门设计的表面活性剂包覆的 CdSe/ZnS 量子点很容易在向列液晶(LC)中分散,形成稳定的胶体。混合烷基膦酸酯和树枝状表面活性剂,其中组成分子包含介晶单元,能够形成热力学稳定的胶体,至少稳定 1 年。稳定的胶体是由于量子点周围 LC 有序的扭曲最小化而形成的。

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