USDA-ARS, Eastern Regional Research Center, 600 E. Mermaid Lane, Wyndmoor, PA 19038, USA.
J Environ Manage. 2013 Oct 15;128:594-601. doi: 10.1016/j.jenvman.2013.06.008. Epub 2013 Jul 8.
Aspen Plus(®) based simulation models have been developed to design a pyrolysis process for on-site production and utilization of pyrolysis oil from equine waste at the Equine Rehabilitation Center at Morrisville State College (MSC). The results indicate that utilization of all the available waste from the site's 41 horses requires a 6 oven dry metric ton per day (ODMTPD) pyrolysis system but it will require a 15 ODMTPD system for waste generated by an additional 150 horses at the expanded area including the College and its vicinity. For this a dual fluidized bed combustion reduction integrated pyrolysis system (CRIPS) developed at USDA's Agricultural Research Service (ARS) was identified as the technology of choice for pyrolysis oil production. The Aspen Plus(®) model was further used to consider the combustion of the produced pyrolysis oil (bio-oil) in the existing boilers that generate hot water for space heating at the Equine Center. The model results show the potential for both the equine facility and the College to displace diesel fuel (fossil) with renewable pyrolysis oil and alleviate a costly waste disposal problem. We predict that all the heat required to operate the pyrolyzer could be supplied by non-condensable gas and about 40% of the biochar co-produced with bio-oil. Techno-economic Analysis shows neither design is economical at current market conditions; however the 15 ODMTPD CRIPS design would break even when diesel prices reach $11.40/gal. This can be further improved to $7.50/gal if the design capacity is maintained at 6 ODMTPD but operated at 4950 h per annum.
基于 Aspen Plus(®)的模拟模型已被开发用于设计马康复中心(Morrisville State College 马萨诸塞州立学院)现场生产和利用马废物热解油的热解工艺。结果表明,利用该场地 41 匹马的所有可用废物需要一个每天 6 干公吨(ODMTPD)的热解系统,但对于扩建区域(包括学院及其周边地区)的另外 150 匹马产生的废物,则需要一个 15 ODMTPD 系统。对于这一点,美国农业部农业研究服务局(ARS)开发的双流体化床燃烧还原集成热解系统(CRIPS)被确定为生产热解油的首选技术。Aspen Plus(®)模型进一步用于考虑在现有的锅炉中燃烧产生的热解油(生物油),这些锅炉为马中心的空间供暖生产热水。模型结果表明,马设施和学院都有可能用可再生的热解油替代柴油燃料(化石燃料),并缓解昂贵的废物处理问题。我们预测,热解器所需的所有热量都可以由不可冷凝气体提供,并且大约 40%的生物油与生物炭一起产生。技术经济分析表明,在当前市场条件下,这两种设计都不具有经济性;然而,当柴油价格达到每加仑 11.40 美元时,15 ODMTPD CRIPS 设计将达到盈亏平衡。如果将设计能力保持在每天 6 干公吨,但每年运行 4950 小时,这个价格可以进一步降低到每加仑 7.50 美元。