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基于三维棉线多级纳米结构的缆式超级电容器用于可穿戴储能。

Cable-type supercapacitors of three-dimensional cotton thread based multi-grade nanostructures for wearable energy storage.

机构信息

Center for Nanoscale Characterization & Devices (CNCD), Wuhan National Laboratory for Optoelectronics (WNLO)-School of Physics, Huazhong University of Science and Technology (HUST), LuoyuRoad 1037, Wuhan 430074, China.

出版信息

Adv Mater. 2013 Sep 20;25(35):4925-31. doi: 10.1002/adma.201301311. Epub 2013 Jul 29.

Abstract

A novel cable-type flexible supercapacitor with excellent performance is fabricated using 3D polypyrrole(PPy)-MnO2 -CNT-cotton thread multi-grade nanostructure-based electrodes. The multiple supercapacitors with a high areal capacitance 1.49 F cm(-2) at a scan rate of 1 mV s(-1) connected in series and in parallel can successfully drive a LED segment display. Such an excellent performance is attributed to the cumulative effect of conducting single-walled carbon nanotubes on cotton thread, active mesoporous flower-like MnO2 nanoplates, and PPy conductive wrapping layer improving the conductivity, and acting as pseudocapacitance material simultaneously.

摘要

一种新型的基于 3D 聚吡咯(PPy)-MnO2 -CNT-棉线多级纳米结构的电极的电缆型柔性超级电容器,具有优异的性能。通过串联和并联连接的具有高面积电容 1.49 F cm(-2) 的多个超级电容器,在扫描速率为 1 mV s(-1) 时,可以成功驱动 LED 段显示器。这种优异的性能归因于导电单壁碳纳米管对棉线、活性介孔花状 MnO2 纳米板和 PPy 导电包裹层的累积效应,提高了导电性,同时充当赝电容材料。

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