Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan.
Chem Commun (Camb). 2013 Sep 18;49(72):7965-7. doi: 10.1039/c3cc44519d. Epub 2013 Jul 31.
The α-fluorovinyl diphenyl sulfonium salt 1 is attractive due to its high potential for the synthesis of mono-fluorinated cyclopropanes and aziridines as useful three-membered rings. The synthetically useful salt 1 is readily prepared from α-fluorovinyl phenyl sulfide and diphenyl iodonium salt in one step.
α-氟代乙烯基二苯砜盐 1 由于其在合成单氟化环丙烷和氮丙啶方面的高潜力而具有吸引力,氮丙啶是一种有用的三元环。合成上有用的盐 1 可以很容易地由α-氟代乙烯基苯硫醚和二苯基碘𬭩盐一步制备得到。