Organisch-Chemisches Institut, University of Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany.
Dalton Trans. 2013 Sep 28;42(36):12861-4. doi: 10.1039/c3dt51777b. Epub 2013 Aug 1.
Bulky and electron-rich N-phosphinomethyl-substituted N-heterocyclic carbene transition metal complexes have been prepared in a short and efficient protocol. The modular synthesis allows one to convert borane-protected phosphino-functionalized imidazolium salts into their corresponding metal chelate complexes in a one-pot procedure.
采用简短高效的方法制备了大体积富电子的 N-膦甲基取代的 N-杂环卡宾过渡金属配合物。该模块化合成方法可将硼烷保护的磷官能化咪唑翁盐一锅法转化为其相应的金属螯合物配合物。
