2-(碘甲基)环丙烷-1,1-二羧酸酯与烯烃和炔烃的分子间可见光光氧化还原原子转移自由基[3+2]环化反应
Intermolecular Visible-Light Photoredox Atom-Transfer Radical [3+2]-Cyclization of 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate with Alkenes and Alkynes.
作者信息
Gu Xiangyong, Li Xiang, Qu Yue, Yang Qi, Li Pixu, Yao Yingming
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering, and Materials Science, Soochow University, 199 RenAi Road, Suzhou, Jiangsu, 215123 (P. R. China), Fax: (+86) 512-65880826.
出版信息
Chemistry. 2013 Sep 2;19(36):11878-82. doi: 10.1002/chem.201301943. Epub 2013 Jul 31.
Radical chemistry! A visible-light-promoted, tin/boron-free intermolecular [3+2] atom-transfer radical cyclization reaction was developed by using iridium polyphenylpridinyl complex as the sensitizer. 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate reacted with various alkenes and alkynes to form cyclopentane and cyclopentene derivatives.
自由基化学！通过使用铱多苯基吡啶基配合物作为敏化剂，开发了一种可见光促进的、无锡/硼的分子间[3+2]原子转移自由基环化反应。2-(碘甲基)环丙烷-1,1-二羧酸酯与各种烯烃和炔烃反应，形成环戊烷和环戊烯衍生物。
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