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钛合金微弧氧化预处理膜层的表面特性及电化学腐蚀行为。

Surface characteristics and electrochemical corrosion behavior of a pre-anodized microarc oxidation coating on titanium alloy.

机构信息

Key Laboratory for Anisotropy and Texture of Materials, Northeastern University, Shenyang 110004, China.

出版信息

Mater Sci Eng C Mater Biol Appl. 2013 Oct;33(7):3775-9. doi: 10.1016/j.msec.2013.05.011. Epub 2013 May 13.

Abstract

A porous bioactive titania coating on biomedical β titanium alloy was prepared by pre-anodization followed by micro arc oxidation technology. The effects of pre-anodization on the phase constituent, morphology and electrochemical corrosion behavior of the microarc oxidation coating were investigated. The results show that pre-anodization has less influence on the phase constituent and the surface morphology of the microarc oxidation coating, but improves the inner layer density of the microarc oxidation coating. The decrease of plasma discharge strength due to the presence of the pre-anodized oxide film contributes to the formation of the compact inner layer. The pre-anodized microarc oxidation coating effectively inhibits the penetration of the electrolyte in 0.9% NaCl solution and thus increases the corrosion resistance of the coated titanium alloy in physiological solution.

摘要

通过预阳极氧化和微弧氧化技术在医用β钛合金上制备多孔生物活性氧化钛涂层。研究了预阳极氧化对微弧氧化涂层的相组成、形貌和电化学腐蚀行为的影响。结果表明,预阳极氧化对微弧氧化涂层的相组成和表面形貌影响较小,但提高了微弧氧化涂层的内层密度。由于存在预氧化膜,等离子体放电强度降低,有助于形成致密的内层。预阳极氧化的微弧氧化涂层可有效阻止电解质在 0.9%NaCl 溶液中的渗透,从而提高了涂层钛合金在生理溶液中的耐腐蚀性。

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