Center for Biomedical Materials and Engineering, Harbin Engineering University, Harbin 150001, China.
Mater Sci Eng C Mater Biol Appl. 2013 Oct;33(7):4266-73. doi: 10.1016/j.msec.2013.06.018. Epub 2013 Jun 26.
The novel interpenetrating (HA+β-TCP)/MgCa composites were fabricated by infiltrating MgCa alloy into porous HA+β-TCP using suction casting technique. The microstructure, mechanical properties and corrosion behaviors of the composites have been evaluated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), mechanical testing, electrochemical and immersion tests. It was shown that the composites had compact structure and the interfacial bonding between MgCa alloy and HA+β-TCP scaffolds was very well. The ultimate compressive strength of the composites was about 500-1000 fold higher than that of the original porous scaffolds, and it still retained quarter-half of the strength of the bulk MgCa alloy. The electrochemical and immersion tests indicated that the corrosion resistance of the composites was better than that of the MgCa matrix alloy, and the corrosion products of the composite surface were mainly Mg(OH)2, HA and Ca3(PO4)2. Meanwhile, the mechanical and corrosive properties of the (HA+β-TCP)/MgCa composites were adjustable by the choice of HA content.
新型互穿(HA+β-TCP)/MgCa 复合材料是通过抽吸铸造技术将 MgCa 合金渗透到多孔 HA+β-TCP 中来制备的。通过扫描电子显微镜(SEM)、X 射线衍射(XRD)、力学性能测试、电化学和浸泡试验对复合材料的微观结构、力学性能和腐蚀行为进行了评估。结果表明,复合材料具有致密的结构,MgCa 合金与 HA+β-TCP 支架之间的界面结合非常好。复合材料的抗压强度约为原始多孔支架的 500-1000 倍,仍保留了块状 MgCa 合金强度的四分之一到一半。电化学和浸泡试验表明,复合材料的耐腐蚀性优于 MgCa 基体合金,复合材料表面的腐蚀产物主要为 Mg(OH)2、HA 和 Ca3(PO4)2。同时,通过选择 HA 含量可以调节(HA+β-TCP)/MgCa 复合材料的力学和腐蚀性。