Department of Natural Resources, Zhejiang University, Zhejiang, China.
Water Sci Technol. 2013;68(3):632-40. doi: 10.2166/wst.2013.173.
The export coefficient model has been applied worldwide to the estimation of non-point source (NPS) pollution. Determining the export coefficients (ECs) from each pollution source and different space-time progressions is problematic because of uncertainty in the ECs of nitrogen from different land-use patterns. Bayesian theory uses the prior probability distribution and likelihood data to generate a posterior probability distribution. The total nitrogen (TN) ECs and stream loss rates K (d(-1)) for five land-use patterns were estimated by combining published results with monthly data for ChangLe River system for 2004-08. After 10(4) iterations, the results had small Markov chain Monte Carlo errors and convergence was obtained. Average TN ECs for the entire watershed were 26.1 ± 8.8, 70.3 ± 9.4, 41.7 ± 6.9, 8.9 ± 1.6 and 6.2 ± 0.5 kg ha(-1) yr(-1) for paddy field, dry land, residential land, woodland and barren land with coefficients of variation (CVs) of 16.9, 6.31, 8.91, 13.3 and 27.9% among sub-catchments respectively. The average K value was 0.33 d(-1) with a CV of 11.3%. Estimated ECs, K and the coupling water quality model were used to predict the years 2008 and 2009; the results validated the model. This Bayesian model can determine ECs using prior knowledge and monitored data, overcoming the problems of the regression model. The model facilitates explicit consideration of uncertainty in NPS management.
该出口系数模型已被广泛应用于非点源(NPS)污染的估算。由于不同土地利用模式下氮的出口系数(ECs)存在不确定性,因此从每个污染源和不同时空进展中确定出口系数(ECs)是有问题的。贝叶斯理论利用先验概率分布和似然数据生成后验概率分布。通过结合发表的结果和 2004-08 年对长乐河流域的每月数据,估计了五种土地利用模式的总氮(TN)ECs 和溪流损失率 K(d(-1))。经过 10(4)次迭代,结果具有较小的马尔可夫链蒙特卡罗误差,并获得了收敛。整个流域的平均 TN ECs 分别为 26.1 ± 8.8、70.3 ± 9.4、41.7 ± 6.9、8.9 ± 1.6 和 6.2 ± 0.5 kg ha(-1) yr(-1),水田、旱地、居民区、林地和荒地的变异系数(CV)分别为 16.9、6.31、8.91、13.3 和 27.9%。平均 K 值为 0.33 d(-1),变异系数为 11.3%。估计的 ECs、K 和耦合水质模型用于预测 2008 年和 2009 年;结果验证了模型。该贝叶斯模型可以使用先验知识和监测数据确定 ECs,克服了回归模型的问题。该模型有利于明确考虑 NPS 管理中的不确定性。