MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Chemistry, Zhejiang University, Hangzhou, 310027, P. R. China.
Adv Mater. 2013 Oct 25;25(40):5725-9. doi: 10.1002/adma.201301654. Epub 2013 Aug 8.
A novel diblock copolymer with a hydrophobic supramolecular polymer block and a hydrophilic traditional polymer block has been prepared. Control over the chain length ratio of the two blocks is obtained by simply changing the concentration proportion of the monomer of the supramolecular polymer block to the traditional polymer block in solution. When the chain length ratio of the two blocks is changed, the formation of various self-assembly morphologies is achieved.
一种新型的两嵌段共聚物，具有疏水性超分子聚合物嵌段和亲水性传统聚合物嵌段。通过简单地改变溶液中超分子聚合物嵌段单体与传统聚合物嵌段单体的浓度比例，可以控制两个嵌段的链长比。当两个嵌段的链长比发生变化时，可以实现各种自组装形态的形成。
