Department of Earth and Planetary Sciences, Harvard University, Cambridge, Massachusetts, United States of America.
Sci Rep. 2013;3:2404. doi: 10.1038/srep02404.
Oscillating chemical reactions are common in biological systems and they also occur in artificial non-biological systems. Generally, these reactions are subject to random fluctuations in environmental conditions which translate into fluctuations in the values of physical variables, for example, temperature. We formulate a mathematical model for a nonisothermal minimal chemical oscillator containing a single negative feedback loop and study numerically the effects of stochastic fluctuations in temperature in the absence of any deterministic limit cycle or periodic forcing. We show that noise in temperature can induce sustained limit cycle oscillations with a relatively narrow frequency distribution and some characteristic frequency. These properties differ significantly depending on the noise correlation. Here, we have explored white and colored (correlated) noise. A plot of the characteristic frequency of the noise induced oscillations as a function of the correlation exponent shows a maximum, therefore indicating the existence of autonomous stochastic resonance, i.e. coherence resonance.
振荡化学反应在生物系统中很常见,它们也存在于人工非生物系统中。一般来说,这些反应受到环境条件随机波动的影响,这会转化为物理变量值的波动,例如温度。我们为包含单个负反馈环的非等温最小化学振荡器制定了一个数学模型,并在没有任何确定性极限环或周期性强制的情况下数值研究温度随机波动的影响。我们表明,温度噪声可以诱导具有相对较窄频率分布和一些特征频率的持续极限环振荡。这些特性取决于噪声相关性而有显著差异。在这里,我们已经探索了白噪声和有色(相关)噪声。作为相关指数函数的噪声诱导振荡的特征频率的图显示出最大值,因此表明存在自主随机共振,即相干共振。