Wuhan National Laboratory for Optoelectronics (WNLO) and College of Optical and Electronic Information, Huazhong University of Science and Technology (HUST), Wuhan 430074, P. R. China.
ACS Nano. 2013 Sep 24;7(9):8051-8. doi: 10.1021/nn4032454. Epub 2013 Aug 12.
The increasing interest in future energy storage technologies has generated the urgent need for alternative rechargeable magnesium ion batteries due to their innate merits in terms of raw abundance, theoretical capacity, and operational safety. Herein, we report an alternative pathway to a new energy storage regime: toward advanced rechargeable magnesium-ion batteries based on WSe2 nanowire-assembled film cathodes. The as-grown electrodes delivered efficient Mg(2+) intercalation/insertion activity, excellent cycling life, enhanced specific capacity, and excellent rate capability. We also evaluated the influence of Mg-intercalation behavior on Mg-ion batteries based on WSe2 film cathodes via the first-principles DFT computations. The results reveal the feasibility of using advanced magnesium-ion batteries based on WSe2 film as energy storage components in next-generation optoelectronic systems.
对未来储能技术日益增长的兴趣,使得人们迫切需要替代的可充电镁离子电池,因为它们在原材料丰富度、理论容量和操作安全性方面具有先天优势。在此,我们报告了一种新的储能途径:基于 WSe2 纳米线组装薄膜正极的先进可充电镁离子电池。所制备的电极表现出高效的 Mg2+ 嵌入/插入活性、优异的循环寿命、增强的比容量和优异的倍率性能。我们还通过第一性原理 DFT 计算评估了 Mg 嵌入行为对基于 WSe2 薄膜正极的镁离子电池的影响。结果表明,基于 WSe2 薄膜的先进镁离子电池有望作为下一代光电子系统中的储能元件。