Department of Chemistry and Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd. Storrs, CT, 06269-3136 (USA).
Angew Chem Int Ed Engl. 2013 Sep 16;52(38):10027-30. doi: 10.1002/anie.201303826. Epub 2013 Aug 12.
IFAB-ulous trifluoromethylation: (CX3COO)2I(III) h (X=F, H) and (CH3COO)3I(V)(C6H4COO) are introduced as CX3·/CX3I precursors for metal-free, visible-light, radical (trifluoro)(iodo)methylations of alkenes, illustrated by their use as photoinitiators for the controlled radical polymerization of vinylidene fluoride with external (I(CF2)6I) and in situ generated (CF3I) iodine chain transfer agents, and for block copolymer synthesis.
IFAB-ulous 三氟甲基化：(CX3COO)2I(III) h (X=F, H) 和 (CH3COO)3I(V)(C6H4COO) 被引入作为 CX3·/CX3I 的前体，用于烯烃的无金属、可见光、自由基（三氟）（碘）甲基化，其用途包括作为光引发剂用于控制自由基聚合偏二氟乙烯与外部（I(CF2)6I）和原位生成（CF3I）碘链转移剂，以及用于嵌段共聚物合成。
