镍(II)/锌和（苯并咪唑基）-6-(1-(芳基亚氨基)乙基)吡啶引发的末端炔烃的环三聚反应。
Cyclotrimerization of terminal alkynes catalyzed by the system of NiCl2/Zn and (benzimidazolyl)-6-(1-(arylimino)ethyl)pyridines.
机构信息
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
出版信息
Dalton Trans. 2013 Oct 7;42(37):13327-30. doi: 10.1039/c3dt51674a. Epub 2013 Aug 13.
PMID:23942891
Abstract
An effective regioselective cyclotrimerization of terminal alkynes is achieved by the direct utilization of NiCl2·6H2O, Zn, and 2-(benzimidazolyl)-6-(1-(arylimino)ethyl)pyridine in one step under ambient temperature.
摘要
在常温下，通过直接利用 NiCl2·6H2O、Zn 和 2-(苯并咪唑基)-6-(1-(芳基亚氨基)乙基)吡啶，实现了末端炔烃的有效区域选择性环三聚反应。
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