Departamento de Química Orgánica, Facultad de Químicas-IRICA, Universidad de Castilla-La Mancha, Campus Universitario, 13071-Ciudad Real, Spain.
Chem Soc Rev. 2014 Jan 7;43(1):58-69. doi: 10.1039/c3cs60164a. Epub 2013 Aug 15.
Very often, chemical transformations require tedious and long procedures, which, sometimes, can be avoided using alternative methods and media. New protocols, enabling us to save time and solvents, allow us also to explore new reaction profiles. This Tutorial Review focuses on the physical and chemical behavior of carbon nanoforms, CNFs (fullerenes, nanotubes, nanohorns, graphene, etc.) when non-conventional methods and techniques, such as microwave irradiation, mechano-chemistry or highly ionizing radiations are employed. In addition, the reactivity of CNFs in non-conventional media such as water, fluorinated solvents, supercritical fluids, or ionic liquids is also discussed.
通常，化学转化需要繁琐且冗长的步骤，而有时可以使用替代方法和介质来避免这些步骤。新的方案不仅使我们能够节省时间和溶剂，还可以探索新的反应途径。本综述教程重点介绍了在非常规方法和技术（例如微波辐射、机械化学或高电离辐射）的应用下，碳纳米形式（富勒烯、纳米管、纳米角、石墨烯等）的物理和化学行为。此外，还讨论了在非常规介质（如水、氟化溶剂、超临界流体或离子液体）中碳纳米形式的反应性。
