Direct Aqueous Dispersion of Carbon Nanotubes Using Nanoparticle-Formed Fullerenes and Self-Assembled Formation of p/n Heterojunctions with Polythiophene.

Single-walled carbon nanotubes (SWCNTs) have received much attention because of their potential in optoelectronic applications. Pristine SWCNTs exhibit substantial van der Waals interactions and hydrophobic characteristics, so precipitation occurs immediately in most organic solvents and water. Highly toxic and hazardous chemicals are often used to obtain well-dispersed SWCNTs. Developing environmentally friendly processing methods for safe and practical applications is a great challenge. Here, we demonstrate direct exfoliation of SWCNTs in pure water only with n-type semiconducting fullerene nanoparticles. The resultant SWCNTs can be well-dispersed in water, where they remain essentially unchanged for several weeks. Adding an aqueous solution of p-type semiconducting water-soluble polythiophene yields self-assembled p/n heterojunctions between polythiophene and the nanoparticles. The aqueous-dispersed SWCNTs yield photocurrent responses in solution-processed thin films as a potential application of water-dispersed carbon nanomaterials.