通过环戊二烯-马来酰亚胺 Diels-Alder 键合作用制备导电聚合物刷的简易途径。
A facile avenue to conductive polymer brushes via cyclopentadiene-maleimide Diels-Alder ligation.
机构信息
Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany.
出版信息
Chem Commun (Camb). 2013 Oct 7;49(77):8623-5. doi: 10.1039/c3cc44683b.
Cyclopentadienyl end-capped poly(3-hexylthiophene) was employed to fabricate conductive surface tethered polymer brushes via a facile route based on cyclopentadiene-maleimide Diels-Alder ligation. The efficient nature of the Diels-Alder ligation was further combined with a biomimetic polydopamine-assisted functionalization of surfaces, making it an access route of choice for P3HT surface immobilization.
环戊二烯封端的聚（3-己基噻吩）通过基于环戊二烯-马来酰亚胺 Diels-Alder 连接的简便方法被用来制备具有导电性的表面接枝聚合物刷。Diels-Alder 连接的高效性质进一步与仿生聚多巴胺辅助的表面功能化相结合，使其成为 P3HT 表面固定化的首选途径。
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