锰卟啉配合物催化的烯烃不对称环氧化反应。
Asymmetric epoxidation of alkenes catalyzed by a porphyrin-inspired manganese complex.
机构信息
Dalian Institute of Chemical Physics, the Chinese Academy of Sciences, Dalian, 116023, People's Republic of China.
出版信息
Org Lett. 2013 Aug 16;15(16):4138-41. doi: 10.1021/ol401812h. Epub 2013 Jul 26.
PMID:23947820
Abstract
A novel strategy for catalytic asymmetric epoxidation of a wide variety of olefins by a porphyrin-inspired chiral manganese complex using H2O2 as a terminal oxidant in excellent yield with up to greater than 99% ee has been successfully developed.
摘要
一种新型策略，使用卟啉启发的手性锰配合物作为催化剂，以 H2O2 作为末端氧化剂，可在优异的收率下（高达 99%ee 以上）对各种烯烃进行催化不对称环氧化。
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