锰卟啉配合物的不对称氧化催化：具有广泛底物范围的高对映选择性亚砜化反应。
Asymmetric oxidation catalysis by a porphyrin-inspired manganese complex: highly enantioselective sulfoxidation with a wide substrate scope.
机构信息
Dalian Institute of Chemical Physics, the Chinese Academy of Sciences , Dalian, 116023, People's Republic of China, Dalian National Laboratory for Clean Energy , People's Republic of China, and University of Chinese Academy of Sciences , Beijing 100049, People's Republic of China.
出版信息
Org Lett. 2013 Nov 15;15(22):5658-61. doi: 10.1021/ol402612x. Epub 2013 Oct 24.
PMID:24156512
Abstract
The first genuinely promising porphyrin-inspired manganese-catalyzed asymmetric sulfoxidation method using hydrogen peroxide has been successfully developed, allowing for rapidly oxidizing (0.5-1.0 h) a wide variety of sulfides in high yields with excellent enantioselectivities (up to >99% ee).
摘要
现已成功开发出第一种真正有前景的卟啉启发的锰催化不对称氧化方法，使用过氧化氢，可以快速（0.5-1.0 h）氧化各种硫醚，产率高，对映选择性极好（高达>99%ee）。
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