Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, People's Republic of China.
Nanoscale Res Lett. 2013 Aug 20;8(1):356. doi: 10.1186/1556-276X-8-356.
Single crystalline one-dimensional (1D) nanostructures of silver telluride (Ag2Te) with well-controlled shapes and sizes were synthesized via the hydrothermal reduction of sodium tellurite (Na2TeO3) in a mixed solution. The morphological evolution of various 1D nanostructures was mainly determined by properly controlling the nucleation and growth process of Ag2Te in different reaction times. Based on the transmission electron microscopy and scanning electron microscopy studies, the formation mechanism for these 1D nanostructures was rationally interpreted. In addition, the current-voltage (I-V) characteristics as a function of magnetic field of the highly single crystal Ag2Te nanowires were systematically measured. From the investigation of I-V characteristics, we have observed a rapid change of the current in low magnetic field, which can be used as the magnetic field sensor. The magneto-resistance behavior of the Ag2Te nanowires with monoclinic structure was also investigated. Comparing to the bulk and thin film materials, we found that there is generally a larger change in R (T) as the sample size is reduced, which indicates that the size of the sample has a certain impact on magneto-transport properties. Simultaneously, some possible reasons resulting in the observed large positive magneto-resistance behavior are discussed.
通过在混合溶液中水热还原碲酸钠(Na2TeO3),合成了具有良好形状和尺寸控制的单晶硅银碲化物(Ag2Te)一维(1D)纳米结构。各种 1D 纳米结构的形态演变主要取决于在不同反应时间下合理控制 Ag2Te 的成核和生长过程。基于透射电子显微镜和扫描电子显微镜研究,合理地解释了这些 1D 纳米结构的形成机制。此外,还系统地测量了高单晶 Ag2Te 纳米线作为磁场函数的电流-电压(I-V)特性。从 I-V 特性的研究中,我们观察到在低磁场下电流的快速变化,这可以用作磁场传感器。还研究了具有单斜结构的 Ag2Te 纳米线的磁阻行为。与体材料和薄膜材料相比,我们发现随着样品尺寸的减小,R(T)的变化通常更大,这表明样品尺寸对磁输运性质有一定的影响。同时,讨论了导致观察到的大正磁阻行为的一些可能原因。