Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, 630090 Novosibirsk, Russia.
Molecules. 2013 Aug 16;18(8):9850-900. doi: 10.3390/molecules18089850.
Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer complexes and radical-anion salts-candidate building blocks of molecule-based electrical and magnetic functional materials.
近期在设计、合成和特性研究方面取得了进展,主要是含硫、硒和碲的 1,2,5-杂氮二硫、硒、碲三元杂环(杂环:S、Se 和 Te)及其稠环衍生物,具有正电子亲和能,可用于制备电子转移配合物和自由基阴离子盐——基于分子的电气和磁性功能材料的候选构筑基块。