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为旧话题注入新活力:硫属-氮 π-杂环作为电子受体。

Breathing some new life into an old topic: chalcogen-nitrogen π-heterocycles as electron acceptors.

机构信息

Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, 630090 Novosibirsk, Russia.

出版信息

Molecules. 2013 Aug 16;18(8):9850-900. doi: 10.3390/molecules18089850.

DOI:10.3390/molecules18089850
PMID:23959195
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6270515/
Abstract

Recent progress in the design, synthesis and characterization of chalcogen-nitrogen π-heterocycles, mostly 1,2,5-chalcogenadiazoles (chalcogen: S, Se and Te) and their fused derivatives, possessing positive electron affinity is discussed together with their use in preparation of charge-transfer complexes and radical-anion salts-candidate building blocks of molecule-based electrical and magnetic functional materials.

摘要

近期在设计、合成和特性研究方面取得了进展,主要是含硫、硒和碲的 1,2,5-杂氮二硫、硒、碲三元杂环(杂环:S、Se 和 Te)及其稠环衍生物,具有正电子亲和能,可用于制备电子转移配合物和自由基阴离子盐——基于分子的电气和磁性功能材料的候选构筑基块。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/f4e707a1fa91/molecules-18-09850-g035.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/e8d0d5623a6f/molecules-18-09850-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/d1caeb61f5a4/molecules-18-09850-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/679bc559661e/molecules-18-09850-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/20c046fe86e0/molecules-18-09850-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/fad797bbe05b/molecules-18-09850-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/d26193212a89/molecules-18-09850-g031.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/43601d3eabc0/molecules-18-09850-g033.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/f4e707a1fa91/molecules-18-09850-g035.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/e8d0d5623a6f/molecules-18-09850-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/d1caeb61f5a4/molecules-18-09850-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/679bc559661e/molecules-18-09850-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/20c046fe86e0/molecules-18-09850-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/fad797bbe05b/molecules-18-09850-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/d26193212a89/molecules-18-09850-g031.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/43601d3eabc0/molecules-18-09850-g033.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56a6/6270515/f4e707a1fa91/molecules-18-09850-g035.jpg

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