通过铜催化的胺和 H-膦酸盐的有氧氧化偶联合成磷酰胺。
Phosphoramidate synthesis via copper-catalysed aerobic oxidative coupling of amines and H-phosphonates.
机构信息
School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
出版信息
Chem Commun (Camb). 2013 Oct 11;49(79):8919-21. doi: 10.1039/c3cc45680c.
PMID:23969724
Abstract
The copper-catalysed oxidative coupling of amines and H-phosphonates to produce phosphoramidates has been achieved using CuI as the catalyst and O2 (present in air) as the sole oxidant.
摘要
铜催化胺和 H-膦酸酯的氧化偶联反应，以生成磷酰胺酯，使用 CuI 作为催化剂，O2（空气中存在的氧气）作为唯一氧化剂。
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