用于合成氨基磷酸酯的无过渡金属胺化磷酰叠氮化物
Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates.
作者信息
Li Qing, Sun Xiaohua, Yang Xiaoqin, Wu Minghu, Sun Shaofa, Chen Xiuling
机构信息
Non-power Nuclear Technology Collaborative Innovation Center, School of Nuclear Technology and Chemistry & Biology, Hubei University of Science and Technology Xianning 437100 China
Xianning Vocational Technical College China.
出版信息
RSC Adv. 2019 May 22;9(28):16040-16043. doi: 10.1039/c9ra03389k. eCollection 2019 May 20.
A facile and efficient approach to phosphoramidates was developed amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available amines as a N source and offers a new opportunity for P-N bond formation.
开发了一种简便高效的制备氨基磷酸酯的方法——磷酰叠氮的胺化反应。在温和的反应体系下，一步即可获得多种氨基磷酸酯，产率良好至优异。该方法使用易于获得的胺作为氮源，为磷氮键的形成提供了新的机会。
Zotero 插件