WestCHEM, School of Chemistry, The University of Glasgow, Glasgow, G12 8QQ, UK.
Adv Mater. 2013 Nov 20;25(43):6245-9. doi: 10.1002/adma.201302565. Epub 2013 Aug 23.
A new family of thiometalate-based composite molecular materials is synthesized and characterized. 1.6 and 1.9 nm-sized clusters are observed in the gas phase utilizing high-resolution ESI-MS. The diversity of the selenite anions as an inorganic ligand is demonstrated by the isolation of the highest nuclearity selenium-based oxothiometalate materials reported so far. The observed proton conductivity of the selenite based oxothiometalate species renders them as promising alternative materials for fuel-cell applications.
一种新的硫属金属酸盐基复合分子材料被合成并进行了表征。利用高分辨率 ESI-MS 在气相中观察到了 1.6 和 1.9nm 大小的团簇。通过分离迄今为止报道的最高核数硒基氧硫属金属酸盐材料，证明了亚硒酸盐阴离子作为无机配体的多样性。所观察到的亚硒酸盐基氧硫属金属酸盐物种的质子电导率使它们成为燃料电池应用有前途的替代材料。
